Raman study of carbon nanotube purification using atmospheric pressure plasma
نویسندگان
چکیده
Multiwalled carbon nanotubes (MWCNTs) were treated with an atmospheric pressure plasma source using an argon/water mixture. Optical emission diagnostics has shown that hydroxyl radicals (OH) were the major reactive species in the plasma. The structural changes in MWCNTs were monitored by micro-Raman spectroscopy. The observed variation of the D and G band intensity ratio and position dispersion with plasma treatment time was ascribed to the change in structural disorder on MWCNT surfaces. Scanning electron microscopic study showed that some defects can be induced in MWCNTs during plasma treatment. Results of thermogravimetric analysis indicated that atmospheric pressure OH plasma is as effective as traditional wet methods for purifying MWCNTs. 2008 Elsevier Ltd. All rights reserved.
منابع مشابه
Numerical Study of Operating Pressure Effect on Carbon Nanotube Growth Rate and Length Uniformity
Chemical Vapor Deposition (CVD) is one of the most popular methods for producing Carbon Nanotubes (CNTs). The growth rate of CNTs based on CVD technique is investigated by using a numerical model based on finite volume method. Inlet gas mixture, including xylene as carbon source and mixture of argon and hydrogen as carrier gas enters into a horizontal CVD reactor at atmospheric pressure. In thi...
متن کاملThe Growth of Multilayer Graphene over MCM-41 by CVD Method in Atmospheric Pressure: metal–Free Nanocatalyst
Graphene films were fabricated over synthesized MCM-41 nanocatalyst by chemical vapordeposition method, and the reaction was carried in atmospheric pressure at 750˚C. Acetylenegas used as a carbon precursor and the synthesis reaction took place in hydrogen atmosphere.Mesoporous MCM-41 was synthesized at room temperature, using wet chemical method. Thesynthesized metal free catalyst was characte...
متن کاملA RIGOROUS COMPARISON OF METHODS FOR MULTI-WALLED CARBON NANOTUBES PURIFICATION USING RAMAN SPECTROSCOPY
Multi-walled carbon nanotubes (MWNT’s) were synthesized using chemical vapor deposition (CVD) method in a fluidized bed reactor under the flow of methane and hydrogen gases. A Cobalt-molybdenum/magnesium oxide (Co-Mo/MgO) nanocatalyst was used as the catalyst of the process. The samples were analyzed using scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The effects of d...
متن کاملNumerical Study of Furnace Temperature and Inlet Hydrocarbon Concentration Effect on Carbon Nanotube Growth Rate
Chemical Vapor Deposition (CVD) is one of the most important methods for producing Carbon Nanotubes (CNTs). In this research, a numerical model, based on finite volume method, is investigated. The applied method solves the conservation of mass, momentum, energy and species transport equations with aid of ideal gas law. Using this model, the growth rate and thickness uniformity of produced CNTs,...
متن کاملNumerical Study of Furnace Temperature and Inlet Hydrocarbon Concentration Effect on Carbon Nanotube Growth Rate
Chemical Vapor Deposition (CVD) is one of the most important methods for producing Carbon Nanotubes (CNTs). In this research, a numerical model, based on finite volume method, is investigated. The applied method solves the conservation of mass, momentum, energy and species transport equations with aid of ideal gas law. Using this model, the growth rate and thickness uniformity of produced CNTs,...
متن کامل